I am telling the way. Just follow it:
First, Copy and paste the code info notepad and save as desktop.inf
''[ExtShellFolderViews]
{BE098140-A513-11D0-
A3A4-00C04FD706EC}=
{BE098140-A513-11D0-
A3A4-00C04FD706EC}
... [{BE098140-
A513-11D0-
A3A4-00C04FD706EC}]
Attributes=1
IconArea_Image=IMG''
Now Replace IMG with the picture name which photo you want to add. (ex: love.png)
Now send the image(love.png) and the desktop.inf file to the pendrive.
Complete! Now enjoy.